I have 1.8v ddr2 sockets in my motherboard as well. I also have two 1.8v ddr2 ram modules installed.
However,
When I first put this thing together, the motherboard was clocked to 2v. I donæt know if this was because somebody over at MSI had a little fun with the motherboard before they shipped it, or if it really
is 2v, but a misprint in their specifications list made it look like a 1.8v.
At first I didn't notice this, and I got the problem that you described. After I clocked it down to 1.8v it worked flawlessly.
As for your question, I don't know.
Seeing as how my 1.8v sockets were 2.0v when I got it and unwrapped it, I would assume there should be no problem to you overclocking the voltage to 2.1v.
Do make a bit of a research though. For example, at 2.1v the motherboard may not be able to use the ram modules full 800mhz to its advantage. But I don't kno.w