Quote: "A vacuum does not insulate energy."
It insulates from thermal conduction very well, I did not say all means of energy transfer.
Quote: "If it did then energy wouldn't travel through space."
You must be talking about electromagnetic radiation, which in this situation is highly minimal.
Quote: "Now, the atmosphere, and any other liquid or gas or solid, can absorb and radiate heat, but heat can still radiate through space."
Via thermal radiation it can, but I was talking about thermal conduction.
Quote: "Think about what you're saying - if a vacuum makes a 'perfect' insulator, then a refrigerator would use a vacuum space to insulate, and would perpetually keep anything inside cold provided that you didn't open it, including the air trapped inside. That's just not how that works. Heat is constantly being exachanged until equillibrium is reached."
It may not be a perfect insulator, but we are talking about relatively low amounts of thermal energy thus the amount of electromagnetic radiation being emitted by the casing will be very low. And for the most part it would be perpetually the same temperature, other than the low amounts of electromagnetic radiation that will be transferred into the inner casing, however for the scope of liquid nitrogen storage this should be more than adequate.
Quote: "Also, if heat couldn't radiate into a vaccum[sic] then the Earth would look like Venus."
Earth(for the most part) does not lose thermal energy via thermal conduction.
Quote: "Liquid hydrogen is impossible to store with today's technology because of the size of the H2 molecule."
Last time I checked space shuttles didn't fail to take off due to their fuel leaking through containment.
Quote: "The cooling effect happens when a liquid turns into a vapor. This is because energy is required for the phase change."
No. It only appears cooler because you have the same amount of molecules occupying a larger space thus the thermal energy per set area will be less, however the total area will expand.
Quote: "The catch, of course, is that if you heat the canister up then it could explode, because the pressure inside the canister will rise dramatically with increased heat."
I'm sure the canister will explode well before the nitrogen becomes a liquid.