ANTIDISESTABLISHMENTARIANISM = the belief which opposes removing the tie between church and state.
HONORIFICABILITUDINITATIBUS = honorableness.
The word first appeared in English in 1599, and in 1721 was listed by Bailey's Dictionary as the longest word in English. It was used by Shakespeare in Love's Labor's Lost (Costard; Act V, Scene I):
"O, they have lived long on the alms-basket of words.
I marvel thy master hath not eaten thee for a word;
for thou art not so long by the head as
honorificabilitudinitatibus: thou art easier
swallowed than a flap-dragon."
Shakespeare does not use any other words over 17 letters in length.
TAUMATAWHAKATANGIHANGAKOAUAUOTAMATEATURIPUKAKAPIKIMAUNGAHORONUKUPOKAIWHENUAKITANATAHU
A hill in New Zealand. This Maori name was in general use, but is now generally abbreviated to Taumata. The name means: the summit of the hill, where Tamatea, who is known as the land eater, slid down, climbed up and swallowed mountains, played on his nose flute to his loved one.
And ofcourse
smiles has a mile betwwen the first and last letters
EDIT:: By christ, look at the size of this one, 1185 letters
ACETYLSERYLTYROSYLSERYLISOLEUCYLTHREONYLSERYLPROLYLSERYLGLUTAMINYLPHENYLALANYLVALYLPHENYLALANYLLEUCYLSERYLSERYLVALYLTRYPTOPHYLALANYLASPARTYLPROLYLISOLEUCYLGLUTAMYLLEUCYLLEUCYLASPARAGINYLVALYLCYSTEINYLTHREONYLSERYLSERYLLEUCYLGLYCYLASPARAGINYLGLUTAMINYLPHENYLALANYLGLUTAMINYLTHREONYLGLUTAMINYLGLUTAMINYLALANYLARGINYLTHREONYLTHREONYLGLUTAMINYLVALYLGLUTAMINYLGLUTAMINYLPHENYLALANYLSERYLGLUTAMINYLVALYLTRYPTOPHYLLYSYLPROLYLPHENYLALANYLPROLYLGLUTAMINYLSERYLTHREONYLVALYLARGINYLPHENYLALANYLPROLYLGLYCYLASPARTYLVALYLTYROSYLLYSYLVALYLTYROSYLARGINYLTYROSYLASPARAGINYLALANYLVALYLLEUCYLASPARTYLPROLYLLEUCYLISOLEUCYLTHREONYLALANYLLEUCYLLEUCYLGLYCYLTHREONYLPHENYLALANYLASPARTYLTHREONYLARGINYLASPARAGINYLARGINYLISOLEUCYLISOLEUCYLGLUTAMYLVALYLGLUTAMYLASPARAGINYLGLUTAMINYLGLUTAMINYLSERYLPROLYLTHREONYLTHREONYLALANYLGLUTAMYLTHREONYLLEUCYLASPARTYLALANYLTHREONYLARGINYLARGINYLVALYLASPARTYLASPARTYLALANYLTHREONYLVALYLALANYLISOLEUCYLARGINYLSERYLALANYLASPARAGINYLISOLEUCYLASPARAGINYLLEUCYLVALYLASPARAGINYLGLUTAMYLLEUCYLVALYLARGINYLGLYCYLTHREONYLGLYCYLLEUCYLTYROSYLASPARAGINYLGLUTAMINYLASPARAGINYLTHREONYLPHENYLALANYLGLUTAMYLSERYLMETHIONYLSERYLGLYCYLLEUCYLVALYLTRYPTOPHYLTHREONYLSERYLALANYLPROLYLALANYLSERINE = Tobacco Mosaic Virus, Dahlemense Strain.
This word has appeared in the American Chemical Society's Chemical Abstracts and is thus considered by some to be the longest real word.
Formely play2kill
When the power of love overcomes the love of the power... the world will know peace. - Jimi Hendrix